Nouns

(n)volunteer, military volunteer, voluntary(military) a person who freely enlists for service
(n)voluntarycomposition (often improvised) for a solo instrument (especially solo organ) and not a regular part of a religious service or musical performance

Adjectives

(a)voluntaryof your own free will or design; done by choice; not forced or compelled“man is a voluntary agent”, “participation was voluntary”, “voluntary manslaughter”, “voluntary generosity in times of disaster”, “voluntary social workers”, “a voluntary confession”
(a)voluntarycontrolled by individual volition“voluntary motions”, “voluntary muscles”