Adjectives

(s)veryprecisely as stated“the very center of town”
(s)identical, selfsame, verybeing the exact same one; not any other:“this is the identical room we stayed in before”, “saw the selfsame quotation in two newspapers”, “on this very spot”, “the very thing he said yesterday”, “the very man I want to see”

Adverbs

(r)very, really, real, rattlingused to give emphasis“she was very gifted”, “he played very well”, “a really enjoyable evening”, “I'm real sorry about it”, “a rattling good yarn”
(r)veryprecisely so“on the very next page”, “he expected the very opposite”