Adjectives

(s)one-on-onedirectly between two individuals“one-on-one instruction”
(s)one-on-one, man-to-manbeing a system of play in which an individual defensive player guards an individual offensive player“one-on-one defense”

Adverbs

(r)one-on-one, person-to-person(of two persons) in direct encounter“preferred to settle the matter one-on-one”, “interviewed her person-to-person”