Adjectives

(s)askew, awry, cockeyed, lopsided, wonky, skew-whiffturned or twisted toward one side“a … youth with a gorgeous red necktie all awry” (G.K.Chesterton), “his wig was, as the British say, skew-whiff”
(s)amiss, awry, haywire, wrongnot functioning properly“something is amiss”, “has gone completely haywire”, “something is wrong with the engine”

Adverbs

(r)awry, amissaway from the correct or expected course“something has gone awry in our plans”, “something went badly amiss in the preparations”
(r)askew, awry, skew-whiffturned or twisted to one side“rugs lying askew”, “with his necktie twisted awry”