Adjectives

(s)askew, awry, cockeyed, lopsided, wonky, skew-whiffturned or twisted toward one side“a...youth with a gorgeous red necktie all awry” (G.K.Chesterton), “his wig was, as the British say, skew-whiff”
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(s)amiss, awry, haywire, wrongnot functioning properly“something is amiss”, “has gone completely haywire”, “something is wrong with the engine”
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Adverbs

(r)awry, amissaway from the correct or expected course“something has gone awry in our plans”, “something went badly amiss in the preparations”
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(r)askew, awry, skew-whiffturned or twisted to one side“rugs lying askew”, “with his necktie twisted awry”
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